COMPUTATIONAL SIMULATION OF THE COMBUSTION OF GREEN HYDROGEN – HYDROCARBONS MIXTURES FOR ENERGY PERFORMANCE AND CARBON DIOXIDE EMISSIONS

Authors

  • Matías Andrés Carrión-Salazar Universidad de La Serena
  • Daniel Felipe Sempértegui-Tapia Universidad Privada Boliviana
  • Cristian Chávez-Toro Universidad de La Serena

DOI:

https://doi.org/10.23881/idupbo.025.1-9i

Keywords:

Green hydrogen, Combustion, Energy performance, Carbon dioxide emissions

Abstract

Bolivia, like other developing countries, faces the challenge of reducing its dependence on fossil fuels and moving toward a cleaner energy matrix. In this context, green hydrogen emerges as a viable alternative, although its implementation still requires local research. Countries such as Chile have already taken significant steps through policies like the National Green Hydrogen Strategy, which promotes its use in various applications, including combustion. This work aligns with that line of development by presenting the computational modeling of the combustion of green hydrogen blended with four selected hydrocarbons: methane, liquefied petroleum gas (LPG), octane, and ethanol. For this purpose, a Python code was developed to estimate the physicochemical properties across the entire range of mixtures, which are then integrated into thermodynamic simulations performed in OpenModelica using the ThermoSysPro library. Subsequently, the results are processed using another Python code, enabling the analysis of mass fractions of combustion products under stoichiometric conditions with a 10% excess of air, the degree of decarbonization as a function of hydrogen mass fraction and flow rate, the energy generated with and without accounting for thermal losses, the higher and lower heating values (HHV and LHV), and the Wobbe index in the cases of methane and LPG. The results show that decarbonization depends directly on the carbon content of the base hydrocarbon, and that the addition of hydrogen increases the energy generated per unit mass, reinforcing its potential as an energy vector in the transition toward more sustainable systems.

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Author Biographies

  • Matías Andrés Carrión-Salazar, Universidad de La Serena
    Departamento de Ingeniería Mecánica
  • Daniel Felipe Sempértegui-Tapia, Universidad Privada Boliviana
    Laboratorio de Energías Alternativas (LEA)
  • Cristian Chávez-Toro, Universidad de La Serena
    Departamento de Ingeniería Mecánica

References

[1] M. Gallardo and R. Barra, “Cambio climático global,” Universidad de Centro de Concepción, 1997.

[2] ACCIONA, “El hidrógeno verde: La energía del futuro clave en la descarbonización.” [Online]. Available: https://www.acciona.com/es/hidrogeno-verde.

[3] Z. Al-Hamamre and J. Yamin, “The effect of hydrogen addition on premixed laminar acetylene-hydrogen-air and ethanol-hydrogen-air flames,” Int J Hydrogen Energy, vol. 38, no. 18, pp. 7499–7509, Jun. 2013, doi: 10.1016/j.ijhydene.2013.03.125.

[4] M. K. G. Gheshlaghi and A. M. Tahsini, “Numerical investigation of hydrogen addition effects to a methane-fueled high-pressure combustion chamber,” Int J Hydrogen Energy, vol. 48, no. 86, pp. 33732–33745, 2023, doi: 10.1016/j.ijhydene.2023.05.119.

[5] H. Ishaq and I. Dincer, “A comprehensive study on using new hydrogen-natural gas and ammonia-natural gas blends for better performance,” J Nat Gas Sci Eng, vol. 81, 2020, doi: 10.1016/j.jngse.2020.103362.

[6] B. Breer et al., “Numerical investigation of NOx production from premixed hydrogen/methane fuel blends,” Combust Flame, vol. 255, 2023, doi: 10.1016/j.combustflame.2023.112920

[7] G. Ali, T. Zhang, W. Wu, and Y. Zhou, “Effect of hydrogen addition on NOx formation mechanism and pathways in MILD combustion of H2-rich low calorific value fuels,” Int J Hydrogen Energy, vol. 45, no. 15, pp. 9200–9210, 2020, doi: 10.1016/j.ijhydene.2020.01.027.

[8] M. N. Rahman, N. Shahril, S. Yusup, and I. Shariff, “Hydrogen Co-Firing Characteristics in a Single Swirl Burner: A Numerical Analysis,” IOP Conf Ser Mater Sci Eng, vol. 1257, no. 1, p. 012020, Oct. 2022, doi: 10.1088/1757-899x/1257/1/012020.

[9] K. Bayramoğlu, A. Bahlekeh and K. Masera, “Numerical investigation of the hydrogen, ammonia and methane fuel blends on the combustion emissions and performance,” Int J Hydrogen Energy, vol. 48, no. 99, pp. 39586–39598, 2023, doi: 10.1016/j.ijhydene.2023.06.079.

[10] H. Rashid, Q. Zhu, M. Rauf, and A. Oppong, “Towards cleaner combustion of hydrocarbons by blending with ammonia and hydrogen using CFD-Based emissions minimization,” Results in Engineering, vol. 27, 2025, doi: 10.1016/j.rineng.2025.105604.

[11] B. Wang, C. Yang, H. Wang, D. Hu, B. Duan, and Y. Wang, “Study on Combustion and Emission Performance of Dual Injection Strategy for Ammonia/Hydrogen Dual-Fuel Engine,” in Journal of Physics: Conference Series, 2023. doi: 10.1088/1742-6596/2437/1/012027.

[12] G. Wobbe, “La definizione della qualità del gas,” L’industria del gas e degli acquedotti, vol. XV, no. 11, pp. 165–172, Rome, Italy, 1926.

[13] A. Cicchitti, C. Lombardi, and M. Silvestri, “Two-phase cooling experiments: pressure drop, heat transfer and burnout measurements,” Energ. Nucl., vol. 7, pp. 417–425, 1960, [Online]. Available: http://www.osti.gov/energycitations/product.biblio.jsp?osti_id=4181977.

[14] Y. A. Cengel, and M. A. Boles, Thermodynamics: An engineering approach, 8va Edición. México, 2015.

[15] H. Copete, A. Amell, and F. Cadavid, “Simulación numérica de una cámara de combustión de alta velocidad con dos configuraciones de inyección de combustible,” Dyna, vol. 75, no. 156, pp. 109–120, 2008.

[16] CoolProp Development Team, "CoolProp", version 6.6.0, 2024. [Online]. Available: https://coolprop.org .

Published

2025-08-25

Issue

Section

Ingenierías

How to Cite

Carrión-Salazar, M. A., Sempértegui-Tapia, D. F., & Chávez-Toro, C. (2025). COMPUTATIONAL SIMULATION OF THE COMBUSTION OF GREEN HYDROGEN – HYDROCARBONS MIXTURES FOR ENERGY PERFORMANCE AND CARBON DIOXIDE EMISSIONS. Revista Investigación & Desarrollo, 25(1), 107-117. https://doi.org/10.23881/idupbo.025.1-9i